Interested

• spectroscopy
• chemometrics
• organic chemistry
• amides
• general chemistry
• cross coupling
• amide bond
• n−c activation
• n–c activation
• n c o activation

Scientific discipline

• chemical sciences

Latest publications

• Acyl fluorides as direct precursors to fluoride ketyl radicals: reductive deuteration using SmI₂ and D₂O.
• ¹⁷O NMR and ¹⁵N NMR chemical shifts of sterically-hindered amides: ground-state destabilization in amide electrophilicity.
• CAAC–IPr*: easily accessible, highly sterically-hindered cyclic (alkyl)(amino)carbenes
• IPr# – highly hindered, broadly applicable N-heterocyclic carbenes.
• L‐Shaped Heterobidentate Imidazo[1,5‐a]pyridin‐3‐ylidene (N,C)‐Ligands for Oxidant‐Free Au^I/Au^III Catalysis
• ItOct (ItOctyl) – pushing the limits of ItBu: highly hindered electron-rich N-aliphatic N-heterocyclic carbenes
• Copper(I)–thiazol-2-ylidenes: highly reactive N-heterocyclic carbenes for the hydroboration of terminal and internal alkynes. Ligand development, synthetic utility, and mechanistic studies
• Structures of the Most Twisted Thioamide and Selenoamide: Effect of Higher Chalcogens of Twisted Amides on N−C(X) Resonance
• Wingtip‐Flexible N‐Heterocyclic Carbenes: Unsymmetrical Connection between IMes and IPr
• Palladium-NHC (NHC = N-heterocyclic Carbene)-Catalyzed Suzuki–Miyaura Cross-Coupling of Alkyl Amides.
• Ring-opening olefin metathesis of twisted amides: activation of amide bonds by C═C cleavage.
• N-acylcarbazoles and N-acylindoles: electronically activated amides for N–C(O) cross-coupling by N_lp to Ar conjugation switch.
• Preference of cis-thioamide structure in N-thioacyl-N-methylanilines.
• Quantitative Determination of Diosmin in Tablets by Infrared and Raman Spectroscopy
• Comparative profiling of serum biomarkers and ATR-FTIR spectroscopy for differential diagnosis of patients with rheumatoid and psoriatic arthritis − a pilot study
• [IPr#–PEPPSI]: A Well-Defined, Highly Hindered and Broadly Applicable Pd(II)–NHC (NHC = N-Heterocyclic Carbene) Precatalyst for Cross-Coupling Reactions
• Sterically hindered ketones via palladium-catalyzed Suzuki–Miyaura cross-coupling of amides by N–C(O) activation.
• IPr*^Oxa – a new class of sterically-hindered, wingtip-flexible N,C-chelating oxazole-donor N-heterocyclic carbene ligands
• [Au(Np^#)Cl]: highly reactive and broadly applicable Au_(I)–NHC catalysts for alkyne π-activation reactions
• Chemistry of bridged lactams: recent developments.